KEGG   REACTION: R06641
Entry
R06641                      Reaction                               
Definition
Malonamoyl-CoA + 8 Malonyl-CoA + Acyl-carrier protein <=> 18-Carbamoyl-3,5,7,9,11,13,15,17-octaoxooctadecanoyl-[acp] + 8 CO2 + 9 CoA
Equation
C06625 + 8 C00083 + C00229 <=> C12441 + 8 C00011 + 9 C00010
Comment
minimal PKS, oxyABC (otcY1-2+otcY1-1+otcY1-3)
There are two proposed pathways for biosynthesis of the malonamate starter unit (see R11516).
Reaction class
RC00004  C00010_C00083  C00010_C06625
RC00039  C00229_C12441
RC02728  C06625_C12441
RC02931  C00083_C12441
RC02932  C00083_C12441
Enzyme
2.3.1.-
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.3  Acyltransferases
   2.3.1  Transferring groups other than aminoacyl groups
    2.3.1.-
     R06641  Malonamoyl-CoA + 8 Malonyl-CoA + Acyl-carrier protein <=> 18-Carbamoyl-3,5,7,9,11,13,15,17-octaoxooctadecanoyl-[acp] + 8 CO2 + 9 CoA
Orthology
K05551  minimal PKS ketosynthase (KS/KS alpha) [EC:2.3.1.- 2.3.1.260 2.3.1.235]
K05552  minimal PKS chain-length factor (CLF/KS beta) [EC:2.3.1.- 2.3.1.260 2.3.1.235]
K05553  minimal PKS acyl carrier protein

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